High Chromium Cast Iron (HCCI) has demonstrated its effectiveness as a potential material for applications in severe environments due to its remarkable wear resistance attributed to the volumetric fraction of carbides in the microstructure. This study investigates a novel high-alloyed composition of white cast iron named High Entropy White Cast Iron (HEWCI), which merges the concepts of HCCI and high entropy alloys. Specifically designed chemical compositions incorporating Vanadium (V), Molybdenum (Mo), and Nickel (Ni) were employed to enhance its wear resistance properties. The solidification path, microstructural characterization, and wear responses of HEWCI were evaluated. XRD and SEM techniques were carried out for characterization purposes. Linearly reciprocating ball-on-flat sliding wear tests were conducted using a high-frequency reciprocation rig (HFRR) tribometer, assessing wear volume, linear wear rate, specific wear rate (κ), and coefficient of friction (COF). The results revealed microstructural refinement and precipitation of new carbides through V, Ni, and Mo additions. This approach demonstrates that adding carbide-forming elements and refining the microstructure are promising strategies for enhancing wear performance in HEWCI alloys.

Abstract Semisolid state processing is a methodology that transforms dendritic as-cast microstructure into globular non-dendritic microstructure with optimized mechanical properties. Rheocasting process involves mechanically stirring metals in a semisolid state and its benefits are associated with processing parameters. In order to evaluate stirring time effects, magnesium alloy MRI 230D (Mg–Al6.45–Ca2.25–Mn0.27–Sr0.25–Sn0.84) was melted and cooled down to semisolid processing temperature (595ºC). Moreover, isothermal stirring was executed for 1, 2, 4 and 8 minutes. In each experiment, cylindrical samples with different diameters (6 and 12 mm) were collected to evaluate cooling rates effects. The microstructure was analyzed through optical and electron microscopes. The results showed that in the longest stirring times, the primary α-Mg phase got coarser and the interglobular region became more refined. Although shape factor initially increased, subsequently there was a tendency to stabilize. Regarding cooling conditions, it was found that the interglobular region became more refined at higher cooling rates. Mechanical tests revealed an initial decrease in ultimate tensile strength (UTS) and ductility, but afterwards increased due to a more regular microstructure and superior shape factor. The 8-minutes stirring sample achieved the best results: an increase of 12% in UTS and 16% in ductility.

ABSTRACT. In order to evaluate how beef buyers in the State of Paraná, Brazil south value meat quality indicators, and attributes of credibility, 519 interviews were conducted in three cities with different sizes (Big - Curitiba, Medium - Campo Mourão and Small - Palotina). The interviews were applied after the meat was placed in the shopping cart and were composed of five questions, including question of spontaneous response: (i) factors that the buyer considers at the purchasing time; (ii) information which the buyer considers important to appear on the meat label; and three questions of stimulated response: (i) preference for meat preparation and exposure for sale, (ii) factors that the buyer considers when purchasing the meat, and (iii) preference for marbling (by photograph) according to the beef preparation. The results showed that beef buyers are more concerned with extrinsic meat quality indicators than the intrinsic ones, especially the meat presentation and hygiene of the sale point; have little knowledge about the factors that positively influence the eating experience of beef and do not cares about attributes of credibility, except for the meat expiration date. Beef buyers from medium (Campo Mourão) and small (Palotina) cities have a similar behavior, and differ from the buyers of a big (Curitiba) city among the attributes surveyed, in relation to the greater appreciation of inspection, tenderness and marbling, and less importance given to the expiration date. Beef buyers prefer meat cut by the butcher; however, this preference is higher in the small city.

RESUMO. Este estudo foi realizado para avaliar o desempenho animal, características de carcaça e qualidade da carne de novilhos Nelore terminados em pastagens e abatidos aos 36 meses de idade (n = 10) e machos não castrados Angus vs. Nelores abatidos aos 20 meses de idade (n = 10). O peso final, peso, características e conformação da carcaça e espessura de gordura de cobertura foram maiores (p < 0,001) para os novilhos Nelores do que para os mestiços Angus vs. Nelores. As perdas de água durante o resfriamento (24 horas, 4º C) foram menores (p < 0,05) para os novilhos Nelores do que para os mestiços Angus vs. Nelores. A percentagem de músculo na 6ª costela foi maior (p < 0,05) para os novilhos Nelores do que para os mestiços Angus vs. Nelores; enquanto que a percentagem de osso foi menor (p < 0,05) para os novilhos Nelores. Após 7 e 14 dias de maturação, o valor de L* da carne foi maior (p < 0,05) para os novilhos Nelores do que para os mestiços Angus vs. Nelores. O valor de L* foi similar (p > 0,05) ao longo da maturação para os mestiços Angus vs. Nelores; enquanto que o valor de L* da carne dos novilhos Nelores aumentou (p < 0,05). O grupo genético não teve efeito (p > 0,05) sobre o valor de a* (cor vermelha). Da mesma forma, o tempo de maturação não teve efeito (p > 0,05) para os animais dos dois grupos genéticos. O grupo genético não teve efeito (p > 0,05) sobre o valor de b* (cor amarela). Por outro lado, o tempo de maturação aumentou o valor de b* após o sétimo dia para os animais dos dois grupos genéticos. A perda por descongelamento e cocção foi menor (p < 0,05) para os novilhos Nelores após o sétimo dia de maturação. A carne dos mestiços Angus vs. Nelores foi mais macia (p < 0,05) em todos os tempos de maturação (1, 4, 7 e 14 dias) do que a carne dos novilhos Nelores. O grupo genético não teve efeito (p > 0,05) sobre a oxidação de lipídeos; no entanto, a oxidação de lipídeos aumentou após o sétimo dia. A carne dos novilhos Nelores continha maior percentagem de ácidos graxos saturados (AGS), menor percentagem de ácidos graxos não saturados (AGNS) e monoinsaturados (AGMI) e similar percentagem de ácidos graxos poli-insaturados (AGPI) do que a carne dos mestiços Angus vs. Nelores. A gordura intramuscular dos Nelores tinha melhor razão n-6:n-3 do que a carne dos mestiços Angus vs. Nelores (4,37 vs. 11,45, respectivamente. A maciez, aroma e aceitabilidade geral foram maiores (p < 0,001) para a carne dos novilhos Nelores, desconsiderando o tempo de maturação (1, 4, 7 e 14 dias).

ABSTRACT. This study evaluated animal performance, carcass characteristics and meat quality of 36-month old Nellore steers finished in pastures (n = 10) and 20-month old Angus vs. Nellore bulls finished in feedlot (n = 10). Final body weight, carcass weight, characteristics, conformation and fat thickness, were higher (p < 0.001) for the Nellore steers than for Angus vs. Nellore bulls. Water losses during chilling (24 hours, 4oC) were lower (p < 0.05) for Nellore steers than for the Angus vs. Nellore bulls. Muscle percentage on the 6th rib was higher (p < 0.05) for the Nellore steers than for Angus vs. Nellore bulls; while bone percentage was lower (p < 0.05) for Nellore steers. After 7 and 14 days of ageing, the L* meat value was higher for the Nellore steers than for the Angus vs. Nellore bulls; the L* meat value was similar (p > 0.05) throughout the ageing period for the Angus vs. Nellore bulls, but higher in meat from the Nellore steers (p < 0.05). Genetic group had no effect (p > 0.05) on meat a* value (redness). Likewise, ageing time had no effect on a* in both genetic groups, and genetic group had no effect (p > 0.05) on meat b* value (yellowness). On the other hand, b* was increased after day 7 of ageing for the bulls from the two genetic groups. Thawing and cooking losses were lower for Nellore steers after day 7 of aging (p < 0.05). The meat of the Angus vs. Nellore bulls was more tender (p < 0.05) at all ageing times studied (1, 4, 7 and 14 days) than the meat of the Nellore steers. Genetic group had no effect (p > 0.05) on lipid oxidation; however, lipid oxidation increased after day7. Meat from Nellore steers contained a higher percentage of saturated fatty acids (SFA), a lower percentage of unsaturated (UFA) and monounsaturated fatty acids (MUFA) and a similar percentage of polyunsaturated fatty acids (PUFA) than the meat from Angus vs. Nellore bulls. Intramuscular fat from Nellore steers had a more favourable n-6:n-3 fatty acid ratio than that from Angus vs. Nellore bulls (4.37 vs. 11.45, respectively). Tenderness, flavour and overall acceptability were higher (p < 0.001) for meats of the Nellore steers, regardless of ageing time (1, 4, 7 and 14 days).

Este trabalho foi realizado para avaliar o desempenho animal e características da carcaça e da carne de novilhas mestiças abatidas com três diferentes pesos vivos. As novilhas foram abatidas com 330 kg (LEV), 360 kg (MED) e 400 kg (PES). O peso vivo final, ganho médio diário e peso de carcaça foram superiores para as novilhas PES, intermediário para as novilhas MED e inferiores para as novilhas LEV. No entanto, o rendimento de carcaça e pH foram semelhantes para os três grupos de animais. As perdas por gotejamento, dissecação e as percentagens de músculo, gordura e ossos na 6ª costela não foram alteradas pelos três pesos de abate. Da mesma forma, o peso de abate não teve efeito sobre a coloração, força de cisalhamento e oxidação lipídica da carne. Em conclusão, novilhas mais pesadas terminadas em pastagem e suplementadas com concentrado apresentaram melhor desempeno animal; todavia, as características de carcaça e qualidade da carne não foram alteradas.

This work was carried out to evaluate the animal performance, carcass characteristics and meat quality of crossbred heifers slaughtered at three different body weights. The heifers were slaughtered with 330 (Light), 360 (Medium) and 400 (Heavy) kg body weight. The final weight, average daily gain and carcass weight were greater for HEA heifers, intermediate for MED heifers and lower for LIG heifers. However, carcass dressing and pH were similar for the three heifers groups. Dripping loss, dissection loss and the muscle, fat and bone percentages on the 6th rib did not alter by slaughter weight. Slaughter weight did not affect the colour, shear force and lipid oxidation of meat. In conclusion, heavy heifers finished in pasture and that were concentrate-supplemented had better animal performance; however, the carcass characteristics and meat quality were similar for the three heifers groups.

A linguiça frescal é um embutido curado que, devido à manipulação durante as etapas de produção, pode se tornar contaminado com S. aureus, patógeno frequentemente relacionado com práticas inadequadas de higiene durante a produção de alimentos. A utilização de nitrito em embutidos tem sua eficácia comprovada contra C. botulinum e, para o S. aureus, estudos indicam que a ação bactericida depende de fatores extrínsecos e intrínsecos. O objetivo do presente estudo foi avaliar o efeito da concentração de nitrito e do pH frente à contaminação por S. aureus e microbiota autóctone em linguiças frescais estocadas em diferente tempos e temperaturas. Linguiças foram produzidas com concentrações de 50, 150 e 200ppm de nitrito e contaminadas com S. aureus. As linguiças foram armazenadas sob refrigeração (7 e 12°C) e a quantificação de S. aureus e psicrotróficos foi realizada nos dias 0, 2, 4, 7 e 10. Os resultados demonstraram que a influência das concentrações de nitrito e temperaturas utilizadas sobre a multiplicação de S. aureus e da microbiota autóctone foi mínima, sendo dependente apenas do período de estocagem. Entretanto, ao final de dez dias, as contagens foram estatisticamente iguais nos grupos analisados, mostrando que as condições de temperatura e concentrações de nitrito utilizadas não exerceram controle efetivo no desenvolvimento destes micro-organismos. Sugere-se que este produto seja armazenado sob temperaturas inferiores a 7°C ou sob congelamento para maior estabilidade microbiológica

Fresh sausages are cured meat products that may be contaminated with Staphylococcus aureus during the manufacturing procedure, which is frequently related with inadequate handling practices. The use of nitrite in meat products has proven efficacy against Clostridium botulinum, and studies indicate that bactericidal action against S. aureus depends on factors that are intrinsic and extrinsic to the product. The objective of the present study was to evaluate the effect of nitrite concentration, and pH on S. aureus and psychrotrophic autochthone microbiota in fresh sausages stored at different times and temperatures. Fresh sausage were produced at nitrite concentrations 50, 150 and 200ppm and contaminated with S. aureus. The sausages were storage at refrigeration (7 and 12°C) and the quantification of S. aureus and psychrotrophic microorganisms was carried out on days 0, 2, 4, 7, and 10. Results showed that nitrite concentrations and the temperatures used had minimal effect on the multiplication of S. aureus and psychrotrophic autochthone microbiota. Final counts depended only on the length of storage: at the end of 10 days, counts were statistically similar in the different groups, showing that temperature and nitrite concentrations used did not control microbial growth effectively. It is suggested that the product should be stored below 7°C or at freezing temperatures for greater microbiological stability

Salmonella é um dos principais agentes de enfermidades transmitidas por alimentos (ETA) no Brasil e em outros países, sendo os derivados cárneos frequentemente associados como veículos de surtos de salmonelose. Um total de 54 cepas de Salmonella sp., isoladas a partir de amostras de salame coletadas nas diferentes etapas de uma linha de produção industrial, foram sorotipadas e posteriormente caracterizadas quanto a sua sensibilidade a antimicrobianos e perfil PFGE. Entre as cepas avaliadas, 11,1% apresentaram resistência a três ou mais dos antimicrobianos, sendo o perfil AmpCStxTe mais freqüente. Foram obtidos 9 e 12 perfis PFGE, empregando-se as enzimas XbaI e SpeI, respectivamente. Os perfis de ambas as enzimas foram agrupados, obtendo-se 12 perfis PFGE combinados que puderam ser separados em dois grupos empregando-se a análise de UPGMA. A linha de produção industrial de salame avaliada apresentou etapas em que há contaminação por diferentes sorotipos de Salmonella sp. Os perfis genéticos encontrados indicam origens distintas para muitas cepas estudadas, uma vez que estes foram pouco relacionados entre si.

Salmonella is one of the most important agents of foodborne disease in Brazil and in other countries, with meat and meat products being identified as important vehicles of salmonelosis. A total of 54 Salmonella strains isolated from a commercial salami processing line were first serotyped and then their antibiotic resistance and macro restriction profiles were determined. 11.1% of the strains showed resistance to 3 or more antibiotics with profile AmpCStxTe being the most frequent. PFGE generated 9 and 12 profiles with enzymes XbaI and SpeI, respectively. It was observed that different serotypes of Salmonella could be found in the different steps of the processing line. The genetic profile of the strains had low relationship indicating the genetic diversity of the tested strains.